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3 cards from this section. Quick, good the night before a test.
What is the Pre-Equilibrium Approximation?
Think about fast steps in reactions.
Why is it useful to express intermediates in terms of reactants?
Consider how we measure reaction rates.
What does the Pre-Equilibrium Approximation treat as being in equilibrium?
Remember the role of speed in reactions.
True or False: The Pre-Equilibrium Approximation is only applicable when all steps have comparable rates.
Consider the relationship of step speeds.
A reaction A + B ⇌ I (fast) → Products (slow) has an equilibrium constant K = 2. However, if the formation of I is slower than anticipated, how might this affect the accuracy of your rate constant calculations?
Consider if the initial step shapes the outcome.
Construct a conceptual map demonstrating how the Pre-Equilibrium Approximation is utilized in complex kinetics and discuss the importance of each component in the mechanism.
Link each component back to how it affects rate laws.
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