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2 cards from this section. Quick, good the night before a test.
What are the two types of bond cleavage?
Think about how the electrons are distributed after the bond breaks.
Define a carbocation.
What do you call a carbon with a positive charge?
What type of cleavage leads to charged particles?
Think about charge distribution.
True or False: A free radical carries a positive charge.
What defines a radical?
Calculate the stability of the following carbocations: CH3+, (CH3)2C+, (CH3)3C+. Justify your ranking.
Consider how many alkyl groups are attached to the positive carbon.
Illustrate the homolytic cleavage of hydrogen peroxide into hydroxyl radicals. Discuss the significance of radical formation.
Use half-headed arrows for radical processes.
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